Highly Diastereoselective SE' Additions of Enantioenriched Allenylstannanes to (S)-2-(Benzyloxy)propanol

DOI: 10.1021/jo00010a007

Source and publish data:

Journal of Organic Chemistry p. 3211 - 3213 (1991)

Update date:2022-07-30

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Authors:

Marshall, James A.

Wang, Xiao-jun

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Article abstract of DOI:10.1021/jo00010a007

The BF3-promoted addition of (S)-allenylstannane (S)-6 to aldehyde 16 afforded a 68:32 mixture of diastereomeric homopropargylic alcohols 17 and 18 whereas MgBr2-promoted addition gave adduct 17 as the exclusive product.The (R)-allenylstannane (R)-6, on t

Full text of DOI:10.1021/jo00010a007

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