Journal of Organic Chemistry p. 3211 - 3213 (1991)
Update date:2022-07-30
Topics:
Marshall, James A.
Wang, Xiao-jun
The BF3-promoted addition of (S)-allenylstannane (S)-6 to aldehyde 16 afforded a 68:32 mixture of diastereomeric homopropargylic alcohols 17 and 18 whereas MgBr2-promoted addition gave adduct 17 as the exclusive product.The (R)-allenylstannane (R)-6, on t
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