Highly Diastereoselective SE' Additions of Enantioenriched Allenylstannanes to (S)-2-(Benzyloxy)propanol

DOI: 10.1021/jo00010a007

Source and publish data:

Journal of Organic Chemistry p. 3211 - 3213 (1991)

Update date:2022-07-30

Topics:

Authors:

Marshall, James A.

Wang, Xiao-jun

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00010a007

The BF3-promoted addition of (S)-allenylstannane (S)-6 to aldehyde 16 afforded a 68:32 mixture of diastereomeric homopropargylic alcohols 17 and 18 whereas MgBr2-promoted addition gave adduct 17 as the exclusive product.The (R)-allenylstannane (R)-6, on t

Full text of DOI:10.1021/jo00010a007

Products guided by the article

Product name:Acetic acid (Z)-(4S,5S,6S)-6-benzyloxy-5-hydroxy-4-methyl-hept-2-enyl ester

Cas No:138124-11-5

R&D Labs maybe for 138124-11-5

Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Wuhan Fortuna Chemical Co.,Ltd

website:http://www.fortunachem.com

Contact:86-27-59207850

Address:Add: Room 2015, No.2 Building, Kaixin Mansion No.107 Jinqiao Avenue, Wuhan, China
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province

Relevant to this article

Aquapalladium complex: A stable and convenient catalyst for the intermolecular hydroamination of alkynes

Doi:10.1002/ejoc.200400568
(2005)
A General Strategy for Site-Selective Incorporation of Deuterium and Tritium into Pyridines, Diazines, and Pharmaceuticals

Doi:10.1021/jacs.7b11710
(2018)
Metallotropic equilibrium and configurational stability of 3-chloro-1-(trimethylsilyl)propargyl and -allenyl metals: Comparative study among lithium, titanium, and zinc

Doi:10.1021/om300420q
(2012)
Synthesis and cyclization of 8-formyl-2-(phenoxymethyl)quinoline-3- carboxylic acids

Doi:10.1002/cjoc.201100420
(2012)
Kinetic hydricity of silane hydrides in the gas phase

Doi:10.1039/c9sc02118c
(2019)
A simple and efficient synthesis of enantiomeric (3aRS,4RS,6aSR)-4-hydroxy- 3,3a,4,6a-tetrahydro-1H-cyclopenta[c]furan-1-ones

Doi:10.1016/j.tet.2012.05.036
(2012)

Article Doi