Tetrahedron Letters p. 5983 - 5986 (1991)
Update date:2022-09-26
Topics:
Hamada, Yasumasa
Tanada, Yoshihisa
Yokokawa, Fumiaki
Shiori, Takayuki
2,3-Dihydroxy-4-dimethylamino-5-methoxypentanoic acid (2) with (2R,3R,4R)-configuration has been stereoselectively prepared from (S)-pyroglutaminol (3) and revealed to be the enantiomer of the compound derived from calyculins (1), which provides the conclusicve evidence on the absolutr configuration of calyculins.
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