Electroreductive Acylation of Benzyl Chlorides with Acid Anhydrides. Stereoselective Formation of (E)-Enol Esters from Benzyl Alkyl Ketones

DOI: 10.1246/cl.1991.2005

Source and publish data:

Chemistry Letters p. 2005 - 2008 (1991)

Update date:2022-08-04

Topics:

Authors:

Nishiguchi, Ikuzo

Oki, Tsuneo

Hirashima, Tsuneaki

Shiokawa, Jiro

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Article abstract of DOI:10.1246/cl.1991.2005

Electroreduction of benzyl chlorides in the presence of acid anhydrides brought about stereoselective formation of (E)-enol esters of the corresponding benzyl alkyl ketones, the initial acylated products, in good to moderate yields.

Full text of DOI:10.1246/cl.1991.2005

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Product name:1-Buten-2-ol, 1-(4-chlorophenyl)-, propanoate, (E)-

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