Optically active triarylboranes: Synthesis and stereoisomerization of ethano-bridged triarylboranes

DOI: 10.1016/0040-4039(91)80170-B

Source and publish data:

Tetrahedron Letters p. 6363 - 6366 (1991)

Update date:2022-08-03

Topics:

Authors:

Okada, Keiji

Inokawa, Haruki

Oda, Masaji

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Article abstract of DOI:10.1016/0040-4039(91)80170-B

Ethano-bridged triarylboranes 1a-c were synthesized. The boranes 1b and lc were resolved into optically pure form (the first example of optical resolution of triarylboranes). The activation parameters of the racemization were determined.

Full text of DOI:10.1016/0040-4039(91)80170-B

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