Synthesis of polysaccharides with 1,2-cis-glycosidic linkages by trityl-thiocyanate polycondensation. Stereoregular α-(1-6)-D-glucan

DOI: 10.1016/S0040-4039(00)74137-2

Source and publish data:

Tetrahedron Letters p. 381 - 384 (1992)

Update date:2022-07-30

Topics:

Authors:

Kochetkov, Nikolay K.

Malysheva, Nelly N.

Klimov, Evgeny M.

Demchenko, Alexey V.

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Article abstract of DOI:10.1016/S0040-4039(00)74137-2

The completely stereoregular polysaccharide, α-(1-6)-D-glucan, has been synthesised using a new highly stereospecific type of polycondensation process - trityl-thiocyanate polycondensation.

Full text of DOI:10.1016/S0040-4039(00)74137-2

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Product name:Acetic acid (2R,3R,4S,5R,6S)-4-acetoxy-5-benzyloxy-6-ethylsulfanyl-2-trityloxymethyl-tetrahydro-pyran-3-yl ester

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