1-Mesityl-2,2,2-trifluoroethanol, an outstanding new chiral controller for catalyzed diels-alder reactions

DOI: 10.1016/0040-4039(91)80420-B

Source and publish data:

Tetrahedron Letters p. 6839 - 6842 (1991)

Update date:2022-08-03

Topics:

Authors:

Corey Corey

Cheng, Xue-Min

Cimprich, Karlene A.

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Article abstract of DOI:10.1016/0040-4039(91)80420-B

The R₂AlCl-catalyzed Diels-Alder reactions of cyclopentadiene with the (R)-1-mesityl-2,2,2-trifluoroethyl esters of acrylic and fumaric acid proceed with ? 97:3 diastereoselectivity.

Full text of DOI:10.1016/0040-4039(91)80420-B

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