Stereoselective Michael Addition Reactions of Acylated Oxazolidinones to Ethyl 3-Trifluoromethylacrylate

DOI: 10.1246/cl.1991.2175

Source and publish data:

Chemistry Letters p. 2175 - 2178 (1991)

Update date:2022-08-05

Topics:

Authors:

Yamazaki, Takashi

Haga, Jiro

Kitazume, Tomoya

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Article abstract of DOI:10.1246/cl.1991.2175

Michael addition reactions of acyl oxazolidinones to ethyl 3-trifluoromethylacrylate were found to proceed smoothly with a high degree of diastereo- as well as diastereofacial selectivity at the new carbon-carbon bond.

Full text of DOI:10.1246/cl.1991.2175

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Product name:Ethyl 3-(trifluoromethyl)-5-<4'-(1''-methylethyl)-2'-oxazolidinon-3'-yl>-5-oxo-4-phenylpentanoate

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