Stereoselective Michael Addition Reactions of Acylated Oxazolidinones to Ethyl 3-Trifluoromethylacrylate

DOI: 10.1246/cl.1991.2175

Source and publish data:

Chemistry Letters p. 2175 - 2178 (1991)

Update date:2022-08-05

Topics:

Authors:

Yamazaki, Takashi

Haga, Jiro

Kitazume, Tomoya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.2175

Michael addition reactions of acyl oxazolidinones to ethyl 3-trifluoromethylacrylate were found to proceed smoothly with a high degree of diastereo- as well as diastereofacial selectivity at the new carbon-carbon bond.

Full text of DOI:10.1246/cl.1991.2175

Products guided by the article

Product name:Ethyl 3-(trifluoromethyl)-5-<4'-(1''-methylethyl)-2'-oxazolidinon-3'-yl>-5-oxo-4-phenylpentanoate

Cas No:138690-10-5

R&D Labs maybe for 138690-10-5

Henan Techway Chemical Co.,Ltd.

website:http://www.techwaychem.com

Contact:+86-371-66380080

Address:No.27 Shunhe Road,
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone
GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Alway Chem, China

website:http://www.alwaychem.com

Contact:+86-532-8586-4000, 8586-5000

Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
Jiangsu Zenji Pharmaceuticals LTD

Contact:+86-025-83172562; +1-224-888-1133(USA)

Address:No.5 Xinmofan Road

Relevant to this article

An improved method for the syntheses of β-substituted cyclohexenones

Doi:10.1080/00397919108021597
(1991)
Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A³-coupling synthesis of propargylamines

Doi:10.1016/j.cclet.2015.05.021
(2015)
Accessibility and selective stabilization of the principal spin states of iron by pyridyl versus phenolic ketimines: Modulation of the ⁶ A ₁ ? ² T ₂ ground-state transformation of the [FeN₄O₂]⁺ chromophore

Doi:10.1021/ic300732r
(2012)
Synthesis of some novel fused imidazo [2, 1-b] [1, 3] thiazole and imidazo [2, 1-b] thiazolo [5, 4-d] isoxazole derivatives

Doi:10.1155/2012/896454
(2012)
Rhodium(iii)-catalyzed oxidative mono- and di-olefination of isonicotinamides

Doi:10.1039/c2ob25773d
(2012)
Stereoselective synthesis of both half segments for (-)-sarcophytonin A and (-)-sarcophytoxide

Doi:10.1248/cpb.39.2514
(1991)

Article Doi