Stereoselective Michael Addition Reactions of Acylated Oxazolidinones to Ethyl 3-Trifluoromethylacrylate

DOI: 10.1246/cl.1991.2175

Source and publish data:

Chemistry Letters p. 2175 - 2178 (1991)

Update date:2022-08-05

Topics:

Authors:

Yamazaki, Takashi

Haga, Jiro

Kitazume, Tomoya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.2175

Michael addition reactions of acyl oxazolidinones to ethyl 3-trifluoromethylacrylate were found to proceed smoothly with a high degree of diastereo- as well as diastereofacial selectivity at the new carbon-carbon bond.

Full text of DOI:10.1246/cl.1991.2175

Products guided by the article

Product name:Ethyl 3-(trifluoromethyl)-5-<4'-(1''-methylethyl)-2'-oxazolidinon-3'-yl>-5-oxo-4-phenylpentanoate

Cas No:138690-10-5

R&D Labs maybe for 138690-10-5

Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou

Relevant to this article

An improved method for the syntheses of β-substituted cyclohexenones

Doi:10.1080/00397919108021597
(1991)
Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A³-coupling synthesis of propargylamines

Doi:10.1016/j.cclet.2015.05.021
(2015)
Accessibility and selective stabilization of the principal spin states of iron by pyridyl versus phenolic ketimines: Modulation of the ⁶ A ₁ ? ² T ₂ ground-state transformation of the [FeN₄O₂]⁺ chromophore

Doi:10.1021/ic300732r
(2012)
Synthesis of some novel fused imidazo [2, 1-b] [1, 3] thiazole and imidazo [2, 1-b] thiazolo [5, 4-d] isoxazole derivatives

Doi:10.1155/2012/896454
(2012)
Rhodium(iii)-catalyzed oxidative mono- and di-olefination of isonicotinamides

Doi:10.1039/c2ob25773d
(2012)
Stereoselective synthesis of both half segments for (-)-sarcophytonin A and (-)-sarcophytoxide

Doi:10.1248/cpb.39.2514
(1991)

Article Doi