Stereoselective synthesis of both half segments for (-)-sarcophytonin A and (-)-sarcophytoxide

DOI: 10.1248/cpb.39.2514

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2514 - 2524 (1991)

Update date:2022-08-05

Topics: Synthesis Column chromatography NMR spectroscopy Stereoselective Asymmetric catalysis Stereochemical Control Chiral synthesis

Authors:

Nishitani

Harada Harada

Sano Sano

Sato Sato

Yamakawa

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Article abstract of DOI:10.1248/cpb.39.2514

A stereoselective synthesis of a dihydrofuran derivative (5) and an allylhalide (8), possible precursors of the cembranes (-)-sarcophytonin A and (-)-sarcophytoxide, is described. The optically active dihydrofuran, right half, segment (49) was synthesized

Full text of DOI:10.1248/cpb.39.2514

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