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Stereoselective synthesis of both half segments for (-)-sarcophytonin A and (-)-sarcophytoxide

DOI: 10.1248/cpb.39.2514

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2514 - 2524 (1991)

Update date:2022-08-05

Topics: Synthesis   Column chromatography   NMR spectroscopy   Stereoselective   Asymmetric catalysis   Stereochemical Control   Chiral synthesis  

Authors:

NishitaniNishitani

HaradaHarada

SanoSano

SatoSato

YamakawaYamakawa

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Article abstract of DOI:10.1248/cpb.39.2514

A stereoselective synthesis of a dihydrofuran derivative (5) and an allylhalide (8), possible precursors of the cembranes (-)-sarcophytonin A and (-)-sarcophytoxide, is described. The optically active dihydrofuran, right half, segment (49) was synthesized

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Full text of DOI:10.1248/cpb.39.2514

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Products guided by the article

Product name:(1S,2R,5S)-7,8-epoxy-2,7-dimethyl-1-(tetrahydropyranyl)oxy-3-cyclohexene

Cas No:138945-42-3

138945-42-3

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