Enantioselective synthesis of carbocyclic showdomycin derivative via asymmetric Diels-Alder reaction of (S(S))-3-(2-pyridylsulphinyl)acrylate

DOI: 10.1016/S0957-4166(00)86154-6

Source and publish data:

Tetrahedron Asymmetry p. 1035 - 1040 (1991)

Update date:2022-08-02

Topics:

Authors:

Takahashi

Kotsubo Kotsubo

Koizumi Koizumi

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Article abstract of DOI:10.1016/S0957-4166(00)86154-6

The first enantioselective synthesis of a carbocyclic analogue of showdomycin, 3-[(1S,2S,3R,4R)-2,3-(isopropylidenedioxy)-4-(pivaloxymethyl)cyclopent yl]maleimide 1, has been accomplished using the asymmetric Diels-Alder reaction of the (S(S))-3-(2-pyridy

Full text of DOI:10.1016/S0957-4166(00)86154-6

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Product name:(1'R,2'S,5'R)-menthyl 2-hydroxy-2-<(1R,2S,3R,4R)-4-(hydroxymethyl)-2,3-(isopropylidenedioxy)cyclopentyl>acetate

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