A FACILE REDUCTIVE DIMERIZATION OF CONJUGATED ACID DERIVATIVES WITH SAMARIUM DIIODIDE

DOI: 10.1016/0040-4039(91)80220-Z

Source and publish data:

Tetrahedron Letters p. 6557 - 6558 (1991)

Update date:2022-07-30

Topics:

Authors:

Inanaga, Junji

Handa, Yuich

Tabuchi, Takanori

Otsubo, Kenji

Yamaguchi, Masaru

Hanamoto, Takeshi

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Article abstract of DOI:10.1016/0040-4039(91)80220-Z

Conjugated esters were instantaneously hydrodimerized at room temperature by use of the reduction system, SmI2-THF-HMPA, in the presence of proton sources.A perfect stereoselection was realized in the reaction of N,N-dibenzyl crotonamide.

Full text of DOI:10.1016/0040-4039(91)80220-Z

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