A general route to spirocycles by radical additions to exocyclic unsaturated sulphides and related compounds

DOI: 10.1016/0040-4039(91)85054-9

Source and publish data:

Tetrahedron Letters p. 7111 - 7114 (1991)

Update date:2022-08-05

Topics: Spirocycles Unsaturated Exocyclic radical additions

Authors:

Mellor, John M.

Mohammed, Shahid

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Article abstract of DOI:10.1016/0040-4039(91)85054-9

Manganic acetate promoted additions of β-dicarbonyl compounds to unsaturated sulphides and enamine derivatives, which are readily available via iodocyclisation of unsaturated substrates, and subsequent elimination, afford spirocyclic systems.

Full text of DOI:10.1016/0040-4039(91)85054-9

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