Direct Synthesis of Isoxazolidinylphosphines by Cycloaddition of Nitrones to Diphenylphosphinoethenes and X-Ray Structure of 7,7-Dimethyl-1-Oxo-1-Phenyl-3-Diphenylphosphinyl-Hexahydro-1H-pyrroloOxazaphosphorine

DOI: 10.1016/S0040-4020(01)86511-X

Source and publish data:

Tetrahedron p. 9083 - 9096 (1991)

Update date:2022-08-03

Topics:

Authors:

Pietrusiewicz, K. Michal

Salamonczyk, Iwona

Wieczorek, Wanda

Brandi, Alberto

Cicchi, Stefano

Goti, Andrea

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Article abstract of DOI:10.1016/S0040-4020(01)86511-X

The 1,3-dipolar cycloaddition reaction of N-alkyl nitrones with diphenylvinylphosphines affords directly isoxazolidinylphosphines in satisfactory yields and in regio- and stereoselective manner.The parent diphenylvinylphosphine was found to favor the form

Full text of DOI:10.1016/S0040-4020(01)86511-X

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