Tetrahedron Letters p. 1423 - 1426 (1992)
Update date:2022-07-30
Topics:
Kadow, John F.
Tun, Min Min
Vyas, Dolatrai M.
Wittman, Mark D.
Doyle, Terrence W.
The stable 12-β-hydroxybicyclo[7.1.0] diynene core 15 has been prepared stereospecifically. The key step consists of conjugate addition of dimethylaluminum benzenethiolate to enone aldehyde 12 followed by an in situ titanium isopropoxide assisted aldol cy
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