Tetrahedron Letters p. 6965 - 6968 (1991)
Update date:2022-08-03
Topics: Conversion Allylic Alcohols Catalysed
Nayyar, Naresh K.
Reddy, M. Madhava
Iqbal, Javed
Secondary and tertiary allylic alcohols can be converted to the corresponding allylically rearranged amides and acetates in presence of a catalytic quantity of cobalt(II) chloride and acetic anhydride in acetonitrile.Tertiary alcohols undergo complete rearrangement whereas the secondary ones yield a mixture of regioisomers.
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