COBALT(II) CHLORIDE CATALYSED CONVERSION OF ALLYLIC ALCOHOLS TO REARRANGED ALLYLIC AMIDES

DOI: 10.1016/0040-4039(91)80456-G

Source and publish data:

Tetrahedron Letters p. 6965 - 6968 (1991)

Update date:2022-08-03

Topics: Conversion Allylic Alcohols Catalysed

Authors:

Nayyar, Naresh K.

Reddy, M. Madhava

Iqbal, Javed

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Article abstract of DOI:10.1016/0040-4039(91)80456-G

Secondary and tertiary allylic alcohols can be converted to the corresponding allylically rearranged amides and acetates in presence of a catalytic quantity of cobalt(II) chloride and acetic anhydride in acetonitrile.Tertiary alcohols undergo complete rearrangement whereas the secondary ones yield a mixture of regioisomers.

Full text of DOI:10.1016/0040-4039(91)80456-G

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