λ3-1H-Phosphirene durch Wasserstoff-Eliminierung von λ3-Phosphiranen

DOI: 10.1016/0040-4039(91)80213-P

Source and publish data:

Tetrahedron Letters p. 6537 - 6538 (1991)

Update date:2022-07-29

Topics:

Authors:

Metternich, H. J.

Niecke, E.

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Article abstract of DOI:10.1016/0040-4039(91)80213-P

A new synthetic route to 1H-phosphirenes is reported.In the reaction of dichlorophosphanes 1a, b with the carbenoid 2 ^tBuMe2Si(H)C(Cl)Li the bis(methylene)phosphoranes RP<=C(H)Si^tBuMe2>2 3a, b are obtained, which rearrange at low tem

Full text of DOI:10.1016/0040-4039(91)80213-P

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