λ3-1H-Phosphirene durch Wasserstoff-Eliminierung von λ3-Phosphiranen

DOI: 10.1016/0040-4039(91)80213-P

Source and publish data:

Tetrahedron Letters p. 6537 - 6538 (1991)

Update date:2022-07-29

Topics:

Authors:

Metternich, H. J.

Niecke, E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80213-P

A new synthetic route to 1H-phosphirenes is reported.In the reaction of dichlorophosphanes 1a, b with the carbenoid 2 ^tBuMe2Si(H)C(Cl)Li the bis(methylene)phosphoranes RP<=C(H)Si^tBuMe2>2 3a, b are obtained, which rearrange at low tem

Full text of DOI:10.1016/0040-4039(91)80213-P

Products guided by the article

Product name:Phenyl-2,3-bis<(tert-butyldimethyl)-silyl>-1Hλ³-phosphiran

Cas No:139067-21-3

R&D Labs maybe for 139067-21-3

Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Beijing eternalchem Co,. Ltd

Contact:+86-10-59484199

Address:No.58-A1026 Liangguan Street
Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province

Relevant to this article

Allyloxy and propargyloxy group migration: Role of remote group participation in the synthesis of 5-C-nucleosides and other sugar derivatives

Doi:10.1021/ol301851q
(2012)
Straightforward access to enantioenriched 2-allylpiperidine: Application to the synthesis of alkaloids

Doi:10.1021/jo202211u
(2012)
The Power of Triplet and Singlet Oxygen in Synthesis: 2-Oxindoles, 3-Hydroxy-2-oxindoles, and Isatins from Furans

Doi:10.1021/acs.orglett.8b01404
(2018)
Benzoxaborole antimalarial agents. Part 3: Design and syntheses of (carboxy-¹³C-3,3-²H₂)-labeled and (3- ¹⁴C)-labeled 7-(2-carboxyethyl)-1,3-dihydro-1-hydroxy-2,1- benzoxaboroles

Doi:10.1002/jlcr.2926
(2012)
Concise, aromatization-based approach to an elaborate C₂- symmetric pyrenophane

Doi:10.1039/c2cc33611a
(2012)
Synthesis of polyfluoroalkyl-containing 1-(4-acetoxybutyl)- and 1-(4-hydroxybutyl)pyrazoles and their tuberculostatic activity

Doi:10.1007/s11172-011-0368-4
(2011)

Article Doi