Synthesis p. 1118 - 1120 (1991)
Update date:2022-08-05
Topics:
Tietze
Beller
Terfort
Dolle
Total synthesis of the natural acetal-β-D-glucoside blepharin (1) and its C-2, epimer 9 by treatment of 2-bromo-2H-1,4-benzoxazin-3(4H)-one (5) with 2,3,4,6-tetra-O-acetyl-β-D-glucopyranose (6) is described. The relative and absolute configuration of 1 was determined by 1H-NMR and X-ray analysis.
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Doi:10.1016/j.tet.2014.09.055
(2014)Doi:10.1021/ja962331a
(1996)Doi:10.1021/om300421m
(2012)Doi:10.1039/c2ob25930c
(2012)Doi:10.1016/j.tet.2012.05.027
(2012)Doi:10.1021/ol302124j
(2012)