Strain-Directed Bridge Cleavage of (Phenylsulfonyl)-7-oxabicycloheptane Derivatives: Application to the Total Synthesis of Carba-α-DL-glucopyranose

DOI: 10.1021/jo00033a002

Source and publish data:

Journal of Organic Chemistry p. 1945 - 1946 (1992)

Update date:2022-08-02

Topics:

Authors:

Acena, Jose Luis

Arjona, Odon

Pradilla, Roberto Fernandez de la

Plumet, Joaquin

Viso, Alma

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Article abstract of DOI:10.1021/jo00033a002

New methodology to prepare highly oxygenated cyclohexenylsulfones by regioselective β-elimination of (phenylsulfonyl)-7-oxabicyclo<2.2.1>heptane derivatives has been developed, and its application to the total synthesis of carba-α-DL-glucopyranose is desc

Full text of DOI:10.1021/jo00033a002

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