
Tetrahedron Letters p. 6847 - 6850 (1991)
Update date:2022-08-05
Topics:
Smith, Amos B.
Gallagher, Rex T.
Keenan, Terence P.
Furst, George T.
Dormer, Peter G.
The complete structures of breynins A and B (1 and 2), orally active hypocholesterolemic glycosides, have been established via NMR analysis and chemical correlation.Breynin B (2) proved to be a sulfoxide derivative of 1, not the isomeric hemithioacetal 3 as proposed previously.
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(1990)