An asymmetric hydroformylation catalyst that delivers branched aldehydes from alkyl alkenes

DOI: 10.1002/anie.201108203

Source and publish data:

Angewandte Chemie - International Edition p. 2477 - 2480 (2012)

Update date:2022-08-03

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Authors:

Noonan, Gary M.

Fuentes, Jose A.

Cobley, Christopher J.

Clarke, Matthew L.

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Article abstract of DOI:10.1002/anie.201108203

Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH₂CH=CH₂ to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde. Copyright

Full text of DOI:10.1002/anie.201108203

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