Erythro-selective aldol reaction of tricarbonyl(η6-o-trialkylsilylbenzaldehyde)chromium(0) complexes with cyclic ketene silyl acetals

DOI: 10.1248/cpb.39.2863

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2863 - 2866 (1991)

Update date:2022-08-05

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Authors:

Mukai Mukai

Mihira Mihira

Hanaoka Hanaoka

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Article abstract of DOI:10.1248/cpb.39.2863

The aldol reaction of tricarbonyl(o-trimethylsilyl (TMS)-benzaldehyde)chromium(0)complex (1a) with cyclic ketene silyl acetals (2-4) afforded the corresponding erythro products selectively. Changing the ortho TMS group to a triisopropylsilyl (TIPS) group

Full text of DOI:10.1248/cpb.39.2863

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