Chemistry Letters p. 61 - 64 (1992)
Update date:2022-07-29
Topics:
Ukaji, Yutaka
Nishimura, Mitsuhiro
Fujisawa, Tamotsu
The Simmons-Smith reaction starting from allylic alcohols using (R,R)-diethyl tartrate as a chiral auxiliary was found to proceed enantioselectively; i.e., the treatment of allylic alcohols with diethylzinc and diethyl tartrate, followed by the reaction with diethylzinc and diiodomethane, afforded the corresponding cyclopropylmethyl alcohols in optically active form.
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