2-Trimethylsilylvinylboranes: Highly reactive and selective Diels-Alder equivalents of 2-trimethylsilylvinyl alcohol and acetylene

DOI: 10.1016/0040-4039(91)80108-I

Source and publish data:

Tetrahedron Letters p. 7365 - 7368 (1991)

Update date:2022-08-06

Topics: Reactive Reactants Diels-Alder Reaction Selective Products

Authors:

Singleton, Daniel A.

Martinez, Jose P.

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Article abstract of DOI:10.1016/0040-4039(91)80108-I

The readily available 2-trimethylsilylvinyl-9-BBN (1) is a highly reactive and selective dienophile. The Diels-Alder products are easily converted into trimethylsilylcyclohexenols and 1,4-cyclohexadienes.

Full text of DOI:10.1016/0040-4039(91)80108-I

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Product name:3-Cyclohexen-1-ol, 4-(1,1-dimethylethyl)-6-(trimethylsilyl)-, trans-

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