The use of trans-2,3-divinyl epoxides as precursors to carbonyl ylides

DOI: 10.1016/0040-4039(91)80552-H

Source and publish data:

Tetrahedron Letters p. 7637 - 7640 (1991)

Update date:2022-08-03

Topics:

Authors:

Chou, Whe-Narn

White, James B.

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Article abstract of DOI:10.1016/0040-4039(91)80552-H

trans-2,3-Divinyl epoxides have been found to be good substrates for the generation of carbonyl ylides in CCl₄ and 145 °C. These ylides, to a limited extent, undergo isomerization to cis-2,3-v divinyl epoxides, leading to the isolation of 4,5-d

Full text of DOI:10.1016/0040-4039(91)80552-H

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