Angewandte Chemie - International Edition p. 6219 - 6222 (2012)
Update date:2022-08-04
Topics:
Shibuya, Tetsuro
Noguchi, Keiichi
Tanaka, Ken
The (de)aroma of success: A cationic platinum(II) complex generated in situ catalyzes dearomatization of fused arenes by forming two intramolecular C-C bonds (see scheme). Mechanistic studies reveal that this reaction could proceed through alkyne activation by the cationic platinum(II) complex followed by a Friedel-Crafts-type reaction. Copyright
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(2012)
