An efficient method for the deprotection of allyl glycosides with adjacent azides: The circumvention of unwanted dipolar cycloaddition products

DOI: 10.1016/0040-4039(91)80109-J

Source and publish data:

Tetrahedron Letters p. 7369 - 7372 (1991)

Update date:2022-08-06

Topics:

Authors:

Lamberth, Clemens

Bednarski, Mark D.

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Article abstract of DOI:10.1016/0040-4039(91)80109-J

A two step deallylation scheme using (bis(methyldiphenylphosphine)) 1,5-cyclooctadiene) iridium (I) hexafluorophosphate and catalytic amounts of osmium tetroxide with trimethylamine N-oxide is used to deprotect allyl glycosides in the presence of an azide

Full text of DOI:10.1016/0040-4039(91)80109-J

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