A Sulfur-assisted Regioselective α-Functionalization of Cyclopropyl Sulfides. Synthetic Applications of Homoallyl Anion Synthon

DOI: 10.1039/c39920000192

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Journal of the Chemical Society. Chemical communications p. 192 - 193 (1992)

Update date:2022-08-02

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Authors:

Takemoto, Yoshiji

Ohra, Taiichi

Yonetoku, Yasuhiro

Imanishi, Takeshi

Iwata, Chuzo

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Article abstract of DOI:10.1039/c39920000192

γ,δ-Unsaturated γ-sulfenyl or sulfinylalkylmercury chlorides 5 and 15, generated from the cyclopropyl sulfide 7 and mercury(II) trifluoroacetate, were demonstrated to be homoallyl anion synthons; these compounds recyclized into the α-functionalized cyclop

Full text of DOI:10.1039/c39920000192

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