Journal of the American Chemical Society p. 3528 - 3534 (1992)
Update date:2022-08-04
Topics: Substituent Effects phenyl esters Antibody-catalyzed hydrolysis Acyl-antibody intermediate
Gibbs, Richard A.
Benkovic, Patricia A.
Janda, Kim D.
Lerner, Richard A.
Benkovic, Stephen J.
The hydrolysis of a series of para-substituted phenyl esters (2 and 6a-d) by the monoclonal catalytic antibody NPN43C9 has been investigated. The apparent pKa observed in the kcat/Km-pH profiles shifts from 8.9 (p-nitrophe
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