Tetrahedron Letters p. 317 - 320 (1992)
Update date:2022-07-29
Topics:
Takacs, James M.
Myoung, Young Chan
The iron-catalyzed cycloisomerization of a chiral (2E,7E) 2,7,9-decatriene derivative bearing a methyl substituent adjacent to the 1,3-diene subunit proceeds with high levels of 1,2-stereoinduction relative to the resident methyl-bearing stereocenter.The stereochemistry of the chiral cyclopentane product is proven by conversion to (-)-Mitsugashiwalactone (1) and (+)-Isoiridomyrmecin (2).
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