Journal of the Chemical Society. Chemical communications p. 672 - 674 (1992)
Update date:2022-08-06
Topics:
Marder, Seth R.
Cheng, Lap-Tak
Tiemann, Bruce G.
The first molecular hyperpolarizabilities (β) of series of 2,6-di-tert-butylindoanilines, measured by electric-field-induced second harmonic generation, are somewhat more sensitive to donor strengh than was found for analogously substituted nitrostilbenes, and dimethylindoaniline has a β roughly twice that of its 2,6-di-tert-butylated analogue, measured in chloroform; solvatochromic measurements on the former compound suggest that that this decrease in hyperpolarizability is consistent with a bound-solvent effect.
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