Chemoselective intramolecular aminocarbonylation of unsaturated amides under Wacker-type conditions

DOI: 10.1016/0040-4039(96)01650-4

Source and publish data:

Tetrahedron Letters p. 7287 - 7290 (1996)

Update date:2022-09-26

Topics:

Authors:

Harayama, Hiroto

Okuno, Hirofumi

Takahashi, Yoshika

Kimura, Masanari

Fugami, Keigo

Tanaka, Shuji

Tamaru, Yoshinao

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Article abstract of DOI:10.1016/0040-4039(96)01650-4

The Wacker-type aminocarbonylation of unsaturated amides shows distinctive dependence of reactivity on the reaction medium: endo nitrogen nucleophiles (endo-carbamates 3 and -ureas 5) undergo aminocarbonylation either in neat methyl orthoacetate (MOA) or

Full text of DOI:10.1016/0040-4039(96)01650-4

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