Synthesis of phosphanyl sulfoximines through phospha-michael reaction of alkenyl sulfoximines and their evaluation as chiral bidentate 1, 5-N, P ligands for palladium in asymmetric allylic alkylation

Article abstract of DOI:10.1002/ejoc.200901462

The intermolecular phospha-Michael reaction of cyclic and acyclic alkenyl sulfoximines proceeds readily and yields the corresponding phosphanyl sulfoximines in good yield. The asymmetric induction provided, by sulfoximine group in C-P bond formation is ap