Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(i) complex

DOI: 10.1039/c2cc34999j

Source and publish data:

Chemical Communications p. 10395 - 10397,3 (2012)

Update date:2022-07-29

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Authors:

Nitadori, Hiroyuki

Ordronneau, Lucie

Boixel, Julien

Boucekkine, Abdou

Guerchais, Veronique

Bozec, Hubert Le

Akita, Munetaka

Singh, Anu

Ledoux, Isabelle

Jacquemin, Denis

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Article abstract of DOI:10.1039/c2cc34999j

The modulation of the quadratic NLO response of an octupolar metal-based chromophore featuring four photochromic dithienylethene units is reported. Quantum mechanical simulations are consistent with a full switching of the DTE units and reproduce the strong enhancement of the NLO response.

Full text of DOI:10.1039/c2cc34999j

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