n-Pentenyl Esters Facilitate and Oxidative Alternative to the Ferrier Rearrangement. An Expeditious Route to Sucrose

DOI: 10.1039/c39920000094

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 94 - 96 (1992)

Update date:2022-07-29

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Authors:

Lopez, J. Cristobal

Fraser-Reid, Bert

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Article abstract of DOI:10.1039/c39920000094

Ferrier-type reactions can now be carried out under non-acidic conditions by treating 3-n-pentenoyl glycals with iodonium dicollidinium perchlorate whereupon the terminal double bond is chemoselectively activated to furnish an allylic oxo-carbenium ion wh

Full text of DOI:10.1039/c39920000094

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