Mechanism of Palladium(II)-Copper(II)-Mediated Demercuration of Cycloalkyl and Cycloalkylmethyl Systems

DOI: 10.1021/jo00035a001

Source and publish data:

Journal of Organic Chemistry p. 2517 - 2519 (1992)

Update date:2022-09-26

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Authors:

Wells, Adam P.

Kitching, William

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Article abstract of DOI:10.1021/jo00035a001

The palladium(II)-copper(II)-mediated demercuration of cycloalkyl- and cycloalkylmethylmercuric chlorides exhibit mechanistic changes as a function of ring size, with elimination-readdition of being important in cyclohexyl systems but direct carbocation formation dominating in cyclooctyl cases.

Full text of DOI:10.1021/jo00035a001

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