Organic and Biomolecular Chemistry p. 8164 - 8174 (2012)
Update date:2022-08-04
Topics:
Yoshino, Madoka
Eto, Kohei
Takahashi, Keisuke
Ishihara, Jun
Hatakeyama, Susumi
The total syntheses of (+)-inthomycin A, (+)-inthomycin B and (-)-inthomycin C, the oxazole-triene antibiotics isolated from Streptomyces sp., have been accomplished via the highly enantio- and stereoselective construction of the C1-C7 (iododienyl)aldol units by taking advantage of a Cinchona alkaloid-catalyzed asymmetric β-lactone synthesis and their isomerisation-free Stille coupling with (E)-5-(3-(tributylstannyl)allyl)oxazole.
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Doi:10.1016/0008-6215(89)85037-2
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(2021)Doi:10.1007/s10593-012-1087-y
(2012)Doi:10.1016/j.tetasy.2012.08.002
(2012)
