Hydroboration of mono-substituted allenes: A general synthetic route to the higher crotylboranes and anti-3-alkyl/aryl-4-hydroxy-1-alkenes

DOI: 10.1016/S0040-4039(96)02255-1

Source and publish data:

Tetrahedron Letters p. 219 - 222 (1997)

Update date:2022-08-03

Topics:

Authors:

Narla, Gowriswari

Brown, Herbert C.

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Article abstract of DOI:10.1016/S0040-4039(96)02255-1

Hydroboration of mono-substituted allenes with Chx₂BH at 0°C leads to the corresponding (E)-substituted allylboranes, known as higher crotylboranes, exclusively. These higher crotylboranes react with aldehydes, and on oxidation, provide the cor

Full text of DOI:10.1016/S0040-4039(96)02255-1

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