Novel Enantioselective Acylating Agents. The Reactions of Chiral Ortho Esters and Silylenol Ethers as a Route to Optically Active Monoprotected 1,3-Dicarbonyl Compounds

DOI: 10.1039/c39900000759

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Journal of the Chemical Society. Chemical communications p. 759 - 760 (1990)

Update date:2022-08-03

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Authors:

Basile, Tiziana

Longobardo, Luigi

Tagliavini, Emilio

Trombini, Claudio

Umani-Ronchi, Achille

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Article abstract of DOI:10.1039/c39900000759

A novel enantioselective route to monoprotected 2-substituted-1,3-dicarbonyl compounds has been developed via acylation of silylenol ethers with chiral ortho esters derived from diethyl or di-isopropyl (R,R)-tartrates; good yields and stereoselectivity ca

Full text of DOI:10.1039/c39900000759

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