Monatshefte fur Chemie p. 99 - 104 (1992)
Update date:2022-08-02
Topics:
Hoz, A. de la
Pardo, C.
Elguero, J.
Jimeno, M. L.
The reaction of tetracyanoethylene oxide on one hand and toluene, chlorobenzene, fluorobenzene, anisole, and nitrobenzene, on the other, has been studied.Toluene and the halogenobenzenes yield mixtures of monoadducts, anisole yield p-methoxyphenylmalononitrile and its dimer and nitrobenzene does not react.These results are discussed with the help of a qualitative orbital model. 1H-NMR analysis of some monoadducts has been carried out.Keywords: Benzene derivatives; Tetracyanoethylene oxide; 1,3-Dipolar cycloaddition.
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