Tetrahedron Letters p. 3049 - 3052 (1989)
Update date:2022-08-02
Topics:
Doyle, Michael P.
High, Kenneth G.
Oon, Su-Min
Osborn, Antonio K.
Diazo compounds formed by thermal or photolytic rearrangement of 3-alkyl-3-phenyl-diazirines in the presence of catalytic amounts of rhodium(II) perfluorobutyrate are effectively directed to metal carbenoid products with minimal competition from processes which are dominant when the diazo compound is used directly or when the diazirine is decomposed in the absence of the catalyst.
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