High degree of exo selectivity in imino Diels-Alder reactions catalyzed by tert-butyldimethylsilyltriflate

DOI: 10.1016/S0040-4039(00)91597-1

Source and publish data:

Tetrahedron Letters p. 1265 - 1268 (1992)

Update date:2022-08-05

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Authors:

Nogue Nogue

Paugam Paugam

Wartski Wartski

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Article abstract of DOI:10.1016/S0040-4039(00)91597-1

Diels-Alder reactions of silyloxydiene 1 derived from 1-acetylcyclohexene with imines 2b and 2c occur with high exo selectivity depending upon experimental conditions: exo cycloadducts 3b-c are exclusively formed under kinetic control using tert-butyldime

Full text of DOI:10.1016/S0040-4039(00)91597-1

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