Tetrahedron Letters p. 7067 - 7070 (1997)
Update date:2022-08-05
Topics:
Maki, Shojiro
Konno, Katsuhiro
Takayama, Hiroaki
Selective oxidation of terminal isopropyl groups to the corresponding tertiary alcohols by an electrochemical method is described. Under the conditions using the TI(TFA)3-hematoporphyrin-O2- cathode reduction system, several substrates such as cholesterol (1) and Grundmann's alcohol (3) gave the corresponding tertiary alcohols 2 and 4, respectively, in reasonable yield.
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Doi:10.1016/S0040-4039(00)70174-2
(1966)Doi:10.1021/om300928j
(2012)Doi:10.1021/om3007008
(2012)Doi:10.1021/ol302802r
(2012)Doi:10.1021/ja8071034
(2008)Doi:10.1016/S0040-4039(00)90501-X
(1967)
