Convenient synthesis of vinyldiazomethanes from α-diazo-β-keto esters and related systems

Article abstract of DOI:10.1080/00397919208019285

A series of vinydiazomethanes were readily prepared by sodium borohydride reduction of α-diazo-β-ketoesters followed by phosphorus oxychloride induced by dehydration of the resulting α-diazo-β-hydroxyesters.

Full text of DOI:10.1080/00397919208019285

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Convenient Synthesis of
Vinyldiazomethanes from
α-Diazo-β-Keto Esters and
Related Systems
Huw M. L. Davies a , Paul W. Hougland a & William R.
Cantrell Jr. a
a Department of Chemistry, Wake Forest University,
Box 7486, Winston-Salem, North Carolina, 27109
Published online: 24 Sep 2006.
To cite this article: Huw M. L. Davies , Paul W. Hougland & William R. Cantrell
Jr. (1992) Convenient Synthesis of Vinyldiazomethanes from α-Diazo-β-Keto
Esters and Related Systems, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 22:7, 971-978, DOI:
10.1080/00397919208019285
To link to this article: http://dx.doi.org/10.1080/00397919208019285
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