Polyfluorinated Aryl Azides as Photoaffinity Labelling Reagents; The Room Temperature CH Insertion Reactions of Singlet Pentafluorophenyl Nitrene With Alkanes

DOI: 10.1016/S0040-4039(00)99647-3

Source and publish data:

Tetrahedron Letters p. 2199 - 2202 (1989)

Update date:2022-08-04

Topics:

Authors:

Young, Mary Jennifer T.

Platz, Matthew S.

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Article abstract of DOI:10.1016/S0040-4039(00)99647-3

Photolysis of pentafluorophenyl azide in alkanes releases singlet pentafluorophenylnitrene which inserts into the CH bond of cyclopentane to produce an adduct in 28percent yield.

Full text of DOI:10.1016/S0040-4039(00)99647-3

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