A Novel C=C Bond Cleavage in Hexacarbonyl(hexapentaene)diiron: X-Ray Crystal Structure of a Bis(μ3,η2-allenylidene)-Iron Complex

DOI: 10.1039/c39920000399

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 399 - 400 (1992)

Update date:2022-08-04

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Authors:

Iyoda, Masahiko

Kuwatani, Yoshiyuki

Oda, Masaji

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Article abstract of DOI:10.1039/c39920000399

Aryl-substituted hexacarbonyl(hexapentaene)diiron complexes undergo facile intramolecular C=C bond cleavage on treatment with to yield the corresponding bis(μ₃,η²-allenylidene)-iron complexes; the X-ray crystal structures of phenyl-substituted bis(μ₃,η²-allenylidene)-iron and related allenylidene complexes are determined.

Full text of DOI:10.1039/c39920000399

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