A Novel C=C Bond Cleavage in Hexacarbonyl(hexapentaene)diiron: X-Ray Crystal Structure of a Bis(μ3,η2-allenylidene)-Iron Complex

DOI: 10.1039/c39920000399

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 399 - 400 (1992)

Update date:2022-08-04

Topics:

Authors:

Iyoda, Masahiko

Kuwatani, Yoshiyuki

Oda, Masaji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000399

Aryl-substituted hexacarbonyl(hexapentaene)diiron complexes undergo facile intramolecular C=C bond cleavage on treatment with to yield the corresponding bis(μ₃,η²-allenylidene)-iron complexes; the X-ray crystal structures of phenyl-substituted bis(μ₃,η²-allenylidene)-iron and related allenylidene complexes are determined.

Full text of DOI:10.1039/c39920000399

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Fe₂(CO)6(C₆H₄(CH₃))4C₆

Cas No:141257-66-1

R&D Labs maybe for 141257-66-1

CGeneTech (Suzhou, China) Co., Ltd.

Contact:+86-512-62956962

Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China

Relevant to this article

Doi:10.1039/j39670000742
(1967)
Copper-Catalyzed Formal Carbene Migratory Insertion into Internal Olefinic C=C Bonds with N-Tosylhydrazones to Access Iminofuran and 2(3H)-Furanone Derivatives

Doi:10.1021/acs.orglett.7b01668
(2017)
LSP2-9166, an orthosteric mGlu4 and mGlu7 receptor agonist, reduces cocaine self-administration under a progressive ratio schedule in rats

Doi:10.1016/j.neulet.2020.135603
(2021)
Synthesis of novel 2-(4-(2-morpholinoethoxy)phenyl)-N-phenylacetamide analogues and their antimicrobial study

Doi:10.1007/s12039-012-0308-3
(2012)
Revision of structure of yellow compound, a reduction product from aequorin, photoprotein in jellyfish, Aequorea aequorea

Doi:10.1016/S0040-4039(00)91607-1
(1992)
Sugara-oligoamides: Synthesis of DNA minor groove binders

Doi:10.1021/jo302238u
(2012)

Article Doi