Radical Annulation Reactions of Allyl Iodomalononitriles

DOI: 10.1016/S0040-4020(01)88882-7

Source and publish data:

Tetrahedron p. 2175 - 2190 (1992)

Update date:2022-08-04

Topics:

Authors:

Curran, Dennis P.

Seong, Churl Min

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)88882-7

Heating of allyl iodomalononitriles with alkenes, followed by tin hydride reduction, forms 1-(cyanoalkyl)-4-cyanocyclopentane rings with up to 5 new stereocenters by a sequence of atom transfer addition followed by nitrile transfer cyclization. Key words:

Full text of DOI:10.1016/S0040-4020(01)88882-7

Products guided by the article

Product name:(3,4-trans)-(2,3-trans)-1,1-dicyano-4-iodomethyl-2-methyl-3-phenyl-cyclopentane

Cas No:141394-46-9

R&D Labs maybe for 141394-46-9

Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Zhejiang Peptites Biotech Co.,Ltd

website:http://www.peptide-china.com

Contact:86-575-83835818

Address:No.8,Hengyizhi Road,Sanjie Town,Shengzhou City,Zhejiang,China
AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
ShangHai BMG Chemical Co., Ltd

Contact:+86-13524845543

Address:Room 602, no 291 sikai road shanghai
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China

Relevant to this article

Reactivity of stable heteroleptic silylene PhC(N t Bu) ₂SiNPh₂ toward diazobenzene and N -benzylidineaniline

Doi:10.1021/om300999e
(2012)
Design, synthesis, and bioevaluation of benzamides: Novel acetylcholinesterase inhibitors with multi-functions on butylcholinesterase, Aβ aggregation, and β-secretase

Doi:10.1016/j.bmc.2012.09.016
(2012)
Mechanosynthesis of amides in the total absence of organic solvent from reaction to product recovery

Doi:10.1039/c2cc36352f
(2012)
Copper-mediated fluoroalkylation of aryl iodides enables facile access to diverse fluorinated compounds: The important role of the (2-Pyridyl)sulfonyl group

Doi:10.1021/ol3029737
(2012)
Developing piperlongumine-directed glutathione S-transferase inhibitors by an electrophilicity-based strategy

Doi:10.1016/j.ejmech.2016.11.034
(2017)
New method for synthesizing the intermediates to 5-HETE from yeast-mediated reduction products by employing Baeyer-Villiger oxidation with complete retention of enantiomeric excess.

Doi:10.1271/bbb.67.1959
(2003)

Article Doi