Radical Annulation Reactions of Allyl Iodomalononitriles

DOI: 10.1016/S0040-4020(01)88882-7

Source and publish data:

Tetrahedron p. 2175 - 2190 (1992)

Update date:2022-08-04

Topics:

Authors:

Curran, Dennis P.

Seong, Churl Min

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Article abstract of DOI:10.1016/S0040-4020(01)88882-7

Heating of allyl iodomalononitriles with alkenes, followed by tin hydride reduction, forms 1-(cyanoalkyl)-4-cyanocyclopentane rings with up to 5 new stereocenters by a sequence of atom transfer addition followed by nitrile transfer cyclization. Key words:

Full text of DOI:10.1016/S0040-4020(01)88882-7

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Product name:(3,4-trans)-(2,3-trans)-1,1-dicyano-4-iodomethyl-2-methyl-3-phenyl-cyclopentane

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