Tetrahedron p. 2495 - 2500 (1992)
Update date:2022-08-04
Topics:
Cerichelli
Freddi
Loreto
Pellacani
Tardella
(Ethocycarbonyl)nitrene (NCO2Et) adds selectively to methyl neryl ether, geranyl methyl ether, and allyl neryl ether. For all the substrates the main product (up to 50%) is the aziridine deriving from addition to the double bond remote from the oxygen atom. Competition experiments point to a different reactivity of the two kind of double bonds and these results are compared with those reported for similar substrates in other addition reactions.
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Doi:10.1016/j.carres.2012.10.001
(2012)Doi:10.1371/journal.pone.0227549
(2020)Doi:10.1021/cn200036s
(2014)Doi:10.1021/ja711010h
(2008)Doi:10.1016/j.tet.2019.03.053
(2019)Doi:10.1021/jo01111a011
(1956)
