Palladium-catalyzed stereocontrolled endo cyclization of 3-hydroxypropyl-1,3-cyclohexadiene leading to versatile fused tetrahydropyrans

DOI: 10.1016/0040-4039(95)00989-P

Source and publish data:

Tetrahedron Letters p. 5397 - 5400 (1995)

Update date:2022-08-04

Topics:

Authors:

Koroleva, Elise B.

Baeckvall, Jan-E.

Andersson, Pher G.

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Article abstract of DOI:10.1016/0040-4039(95)00989-P

A palladium-catalyzed synthesis of stereodefined fused tetrahydropyrans from 2-substituted 1,3-cyclohexadienes is presented. The reaction takes place via an intramolecular 1,4-oxidation of the conjugated diene via a (π-allyl)palladium intermediate. The st

Full text of DOI:10.1016/0040-4039(95)00989-P

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