Contrasting Pathways for the Directed Homogeneous Hydrogenation of Vinyl Sulfoxides and Vinyl Sulfones

DOI: 10.1039/c39920000592

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 592 - 594 (1992)

Update date:2022-08-05

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Authors:

Ando, David

Bevan, Christopher

Brown, John M.

Price, David W.

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Article abstract of DOI:10.1039/c39920000592

Rh-complex catalysed directed hydrogenation of (α-hydroxyalkyl)vinyl sulfones follows the same stereochemical course as the corresponding acrylates, via HO-coordination; hydrogenation of the related (α-hydroxyalkyl)vinyl sulfoxides is directed by S-O coor

Full text of DOI:10.1039/c39920000592

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