Dispiroketals in synthesis: Preparation of a stable, sterically demanding glyceraldehyde ketal and diastereoselective reactions with simple organometallic reagents

DOI: 10.1055/s-1992-34153

Source and publish data:

Synthesis p. 52 - 54 (1992)

Update date:2022-08-05

Topics:

Authors:

Ley Ley

Woods Woods

Zanotti-Gerosa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1992-34153

A preparation of the novel dispiroketal of D-glyceraldehyde is described. The diastereoselective addition of various organometallic reagents proceeds with anti selectivity due to the large steric bulk of the dispiroketal.

Full text of DOI:10.1055/s-1992-34153

Products guided by the article

Product name:(6R,7R,14S)-14-<2-(4-methylphenylsulphonyl)ethyl>-1,8,13,16-tetraoxodispiro<5.0.5.4>-hexadecane

Cas No:141650-90-0

R&D Labs maybe for 141650-90-0

PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China

Relevant to this article

Multifunctional 6-fluoro-3-[3-(pyrrolidin-1-yl)propyl]-1,2-benzoxazoles targeting behavioral and psychological symptoms of dementia (BPSD)

Doi:10.1016/j.ejmech.2020.112149
(2020)
Highly diastereodifferentiating and regioselective [2+2]-photoreactions using methoxyaromatic menthyl cyclohexenone carboxylates

Doi:10.1016/j.tet.2012.10.074
(2013)
Synthesis and characterization of polytriphenylamine based graft polymers for photorefractive application

Doi:10.1016/j.polymer.2012.11.028
(2013)
Absolute Configuration Determination of 2,3-Dihydro-1H,5H-pyrazolo[1,2-a]pyrazoles Using Chiroptical Methods at Different Wavelengths

Doi:10.1021/acs.joc.6b02270
(2016)
Simple one-pot synthesis of new derivatives of the macrocyclic aminal 1,3,7,9,13,15,19,21-octaazapentacyclo-[19.3.1.1^3,7.1 ^9,13.1^15,19]octacosane (OAPO)

Doi:10.1080/00397911.2011.609956
(2013)
Doi:10.1016/0040-4020(63)85007-3
(1963)

Article Doi