Dispiroketals in synthesis: Preparation of a stable, sterically demanding glyceraldehyde ketal and diastereoselective reactions with simple organometallic reagents

DOI: 10.1055/s-1992-34153

Source and publish data:

Synthesis p. 52 - 54 (1992)

Update date:2022-08-05

Topics:

Authors:

Ley Ley

Woods Woods

Zanotti-Gerosa

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Article abstract of DOI:10.1055/s-1992-34153

A preparation of the novel dispiroketal of D-glyceraldehyde is described. The diastereoselective addition of various organometallic reagents proceeds with anti selectivity due to the large steric bulk of the dispiroketal.

Full text of DOI:10.1055/s-1992-34153

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