Diels-Alder Cycloadditions Using Nucleophilic 2-Pyridones. Regiocontrolled and Stereocontrolled Synthesis of Unsaturated, Bridged, Bicyclic Lactams

DOI: 10.1021/jo00041a010

Source and publish data:

Journal of Organic Chemistry p. 4088 - 4097 (1992)

Update date:2022-08-04

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Authors:

Posner, Gary H.

Vinader, Victoria

Afarinkia, Kamyar

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Article abstract of DOI:10.1021/jo00041a010

Captodative 3-oxy- and 3-(tolylthio)-1-tosyl-2-pyridones 1a-1d are shown to be reactive as nucleophilic dienes undergoing 2 + 4-cycloadditions with various electrophilic alkenes under sufficiently mild thermal conditions (90-100 deg C) that the initial bi

Full text of DOI:10.1021/jo00041a010

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